Two new diiridium–triazolylidene complexes were prepared as bimetallic analogues of established mononuclear water oxidation catalysts. Both complexes are efficient catalyst precursors in the presence of cerium ammonium ...
Iridium complexes of Cp* and mesoionic carbene ligands were synthesized and evaluated as potential water oxidation catalysts using cerium(IV) ammonium nitrate as a chemical oxidant. Performance was evaluated by turnover ...
Metalation of a C2-methylated pyridylimidazolium salt with [IrCp*Cl2]2 affords either an ylidic complex, resulting from C(sp3)[BOND]H bond activation of the C2-bound CH3 group if the metalation is performed in the presence ...
The complex IrCl2(Cp*)(trz) (trz = triazolylidene), 2, was prepared from readily available 1,3-dimethyl-4-phenyl-1,2,3-triazolium salt. Under basic conditions, the C-bound phenyl group readily cyclometalates, while under ...
RSS