Browsing by Author Gilheany, Declan G.

Showing results 1 to 11 of 11
Published DateTitleAuthor(s)
Dec-2012Anomalous Z-isomer content in Wittig reaction products from keto-stabilised ylides with ortho-heteroatom substituted benzaldehydesByrne, Peter A.Higham, Lee J.McGovern, PádraicGilheany, Declan G.
11-Oct-2013Cleavage of P=O in the Presence of P-N: Aminophosphine Oxide Reduction with In Situ Boronation of the PIII ProductKenny, Niall P.Rajendran, Kamalraj V.Jennings, Elizabeth V.Gilheany, Declan G.
Mar-2012A convenient and mild chromatography-free method for the purification of the products of Wittig and Appel reactionsByrne, Peter A.Rajendran, Kamalraj V.Muldoon, JimmyGilheany, Declan G.
21-Dec-2012Direct evidence of a multicentre halogen bond: unexpected contraction of the P–XXX–P fragment in triphenylphosphine dihalidesNikitin, KirillMüller-Bunz, HelgeGilheany, Declan G.
Dec-2011An easy and short preparation of pentachloroacetone by selective dechlorination of hexachloroacetone under Appel conditionsRajendran, Kamalraj V.Carr, Damien J.Gilheany, Declan G.
Aug-2012Identification of a key intermediate in the asymmetric Appel process: one pot stereoselective synthesis of P-stereogenic phosphines and phosphine boranes from racemic phosphine oxidesGilheany, Declan G.Rajendran, Kamalraj V.
May-2013The modern interpretation of the Wittig reaction mechanismByrne, Peter A.Gilheany, Declan G.
Feb-2012Simple unprecedented conversion of phosphine oxides and sulfides to phosphine boranes using sodium borohydrideRajendran, Kamalraj V.Gilheany, Declan G.
30-Sep-2013Synthesis of 2,3-Dihydro-1-phenylbenzo[b]phosphole (1-Phenylphosphindane) and Its Use as a Mechanistic Test in the Asymmetric Appel Reaction: Decisive Evidence against Involvement of Pseudorotation in the Stereoselecting StepCarr, Damien J.Kudavalli, Jaya S.Dunne, Katherine S.Müller-Bunz, HelgeGilheany, Declan G.
5-Apr-2012A U-Turn in the Asymmetric Appel Reaction: Stereospecific Reduction of Diastereomerically Enriched Alkoxyphosphonium Salts Allows the Asymmetric Synthesis of P-Stereogenic Phosphanes and Phosphane BoranesRajendran, Kamalraj V.Kudavalli, Jaya S.Dunne, Katherine S.Gilheany, Declan G.
May-2012Unequivocal experimental evidence for a unified lithium salt-free Wittig reaction mechanism for all phosphonium ylide types: reactions with β-heteroatom-substituted aldehydes are consistently selective for cis-oxaphosphetane-derived productsByrne, Peter A.Gilheany, Declan G.