Published Date Title Author(s)
Dec-2012 Anomalous Z-isomer content in Wittig reaction products from keto-stabilised ylides with ortho-heteroatom substituted benzaldehydes Byrne, Peter A.; Higham, Lee J.; McGovern, Pádraic; Gilheany, Declan G.
11-Oct-2013 Cleavage of P=O in the Presence of P-N: Aminophosphine Oxide Reduction with In Situ Boronation of the PIII Product Kenny, Niall P.; Rajendran, Kamalraj V.; Jennings, Elizabeth V.; Gilheany, Declan G.
Mar-2012 A convenient and mild chromatography-free method for the purification of the products of Wittig and Appel reactions Byrne, Peter A.; Rajendran, Kamalraj V.; Muldoon, Jimmy; Gilheany, Declan G.
21-Dec-2012 Direct evidence of a multicentre halogen bond: unexpected contraction of the P–XXX–P fragment in triphenylphosphine dihalides Nikitin, Kirill; Müller-Bunz, Helge; Gilheany, Declan G.
Dec-2011 An easy and short preparation of pentachloroacetone by selective dechlorination of hexachloroacetone under Appel conditions Rajendran, Kamalraj V.; Carr, Damien J.; Gilheany, Declan G.
Aug-2012 Identification of a key intermediate in the asymmetric Appel process: one pot stereoselective synthesis of P-stereogenic phosphines and phosphine boranes from racemic phosphine oxides Gilheany, Declan G.; Rajendran, Kamalraj V.
May-2013 The modern interpretation of the Wittig reaction mechanism Byrne, Peter A.; Gilheany, Declan G.
Feb-2012 Simple unprecedented conversion of phosphine oxides and sulfides to phosphine boranes using sodium borohydride Rajendran, Kamalraj V.; Gilheany, Declan G.
1-Apr-2017 Structure-activity relationship of a novel family of cysteinyl leukotriene receptor antagonist quinoline compounds with anti-angiogenic activity Reynolds, Alison; Ventosa, Pilar; Granander, Johan; Kilty, Claire; Young, Elizabeth; Butler, Clare T.; Galvin, Orla; Merrigan, Stephanie; Sasore, Temitope; Fernandez, Yolanda; Gilheany, Declan G.; Kennedy, Breandán
30-Sep-2013 Synthesis of 2,3-Dihydro-1-phenylbenzo[b]phosphole (1-Phenylphosphindane) and Its Use as a Mechanistic Test in the Asymmetric Appel Reaction: Decisive Evidence against Involvement of Pseudorotation in the Stereoselecting Step Carr, Damien J.; Kudavalli, Jaya S.; Dunne, Katherine S.; Müller-Bunz, Helge; Gilheany, Declan G.
5-Apr-2012 A U-Turn in the Asymmetric Appel Reaction: Stereospecific Reduction of Diastereomerically Enriched Alkoxyphosphonium Salts Allows the Asymmetric Synthesis of P-Stereogenic Phosphanes and Phosphane Boranes Rajendran, Kamalraj V.; Kudavalli, Jaya S.; Dunne, Katherine S.; Gilheany, Declan G.
May-2012 Unequivocal experimental evidence for a unified lithium salt-free Wittig reaction mechanism for all phosphonium ylide types: reactions with β-heteroatom-substituted aldehydes are consistently selective for cis-oxaphosphetane-derived products Byrne, Peter A.; Gilheany, Declan G.