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Matlock, Johnathan V.
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Matlock, Johnathan V.
Official Name
Matlock, Johnathan V.
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- PublicationSynthesis of Isothiocineole and Application in Multi-gram Scale Sulfur Ylide-mediated Asymmetric Epoxidation and Aziridination(Thieme, 2018-07-19)
; ; ; ; The synthesis of the chiral sulfide isothiocineole from limonene and elemental sulfur on multi-gram scale and its alkylation to make >50 g of the corresponding benzylsulfonium salt are described. The application of this salt to the sulfur ylide-mediated asymmetric epoxidation of aldehydes and the asymmetric aziridination of imines on a >5 g scale is demonstrated.426Scopus© Citations 9