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Ryan, Kevin M.
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Ryan, Kevin M.
Official Name
Ryan, Kevin M.
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Now showing 1 - 2 of 2
- PublicationElectrophoretic deposition of poly(3-decylthiophene) onto gold-mounted cadmium selenide nanorods(ACS Publications, 2011-09-21)
; ; ; ; ; Molecular mechanisms of electrophoretic deposition (EPD) of poly(3-decylthiophene) (P3DT) molecules onto vertically aligned cadmium selenide arrays have been studied using large-scale, nonequilibrium molecular dynamics (MD), in the absence and presence of static external electric fields. The field application and larger polymer charges accelerated EPD. Placement of multiple polymers at the same lateral displacement from the surface reduced average deposition times due to “crowding”, giving monolayer coverage. These findings were used to develop and validate Brownian dynamics simulations of multilayer polymer EPD in scaled-up systems with larger inter-rod spacings, presenting a generalized picture in qualitative agreement with random sequential adsorption.Scopus© Citations 6 666 - PublicationA facile spin-cast route for cation exchange of multilayer perpendicularly-aligned nanorod assemblies(RSC publications, 2011-10-07)
; ; ; ; ; ; ; A facile spin cast route was developed to convert perpendicularly aligned nanorod assemblies of cadmium chalcogenides into their silver and copper analogues. The assemblies are rapidly cation exchanged without affecting either the individual rod dimensions or collective superlattice order extending over several multilayers.Scopus© Citations 36 740