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Donnelly, Kate F.
Preferred name
Donnelly, Kate F.
Official Name
Donnelly, Kate F.
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- PublicationRegioselective Electrophilic C-H Bond Activation in Triazolylidene Metal Complexes Containing a N-Bound Phenyl Substituent(American Chemical Society, 2012-11-29)
; ; ; Transmetalation of a 1,4-diphenyl-substituted 1,2,3-triazolylidene silver complex with an electrophilic metal center, e.g., RuII, IrIII, or RhIII, induces spontaneous and chemoselective cyclometalation involving C–H bond activation of the N-bound phenyl group exclusively. Less electrophilic metals such as IrI, RhI, and PtII yield a monodentate triazolylidene complex, while cyclometalation with borderline cases (PdII) or the activation of the C-bound phenyl ring requires acetate as a promoter.Scopus© Citations 68 402