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  5. A new, mild one-pot synthesis of iodinated heterocycles as suitable precursors for N-heterocyclic carbene complexes
 
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A new, mild one-pot synthesis of iodinated heterocycles as suitable precursors for N-heterocyclic carbene complexes

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Download TETL-D-10-01761 ms_rvsd.pdf455.4 KB
Author(s)
Iglesias, Manuel 
Schuster, Oliver 
Albrecht, Martin 
Uri
http://hdl.handle.net/10197/3686
Date Issued
13 October 2010
Date Available
19T15:41:44Z June 2012
Abstract
The use of I2/AgOAc in dichloromethane constitutes a cheap, mild, and efficient method for the selective iodination of a variety of heterocycles. In a number of cases, this method provides superior yields than other literature methods and affords iodo-functionalized heterocycles that are suitable precursors for carbene complexes.
Sponsorship
European Research Council
Other Sponsorship
Swiss National Science Foundation FP7 (Marie Curie Action)
Type of Material
Journal Article
Publisher
Elsevier
Journal
Tetrahedron Letters
Volume
51
Issue
41
Start Page
5423
End Page
5425
Copyright (Published Version)
2010 Elsevier
Keywords
  • Iodination

  • Imidazole

  • N-heterocyclic carben...

  • Oxidative addition

  • Ligand precursors

  • Abnormal carbene comp...

Subject – LCSH
Heterocyclic compounds
Imidazoles
Carbenes (Methylene compounds)
DOI
10.1016/j.tetlet.2010.07.178
Language
English
Status of Item
Peer reviewed
This item is made available under a Creative Commons License
https://creativecommons.org/licenses/by-nc-sa/1.0/
Owning collection
Chemistry Research Collection
Scopus© citations
12
Acquisition Date
Feb 3, 2023
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