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  5. The influence of SO2-/4 on the catalytic combustion of soot using O-2 and NO/O-2 mixtures over Na-promoted Al2O3 catalysts
 
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The influence of SO2-/4 on the catalytic combustion of soot using O-2 and NO/O-2 mixtures over Na-promoted Al2O3 catalysts

Author(s)
Sullivan, James A.  
Keane, Orla  
Maguire, Linda  
Uri
http://hdl.handle.net/10197/4002
Date Issued
2005-07
Date Available
2013-01-11T14:53:25Z
Abstract
Na/Al2O3 catalysts are tested in the soot oxidation reaction using O-2 and NO/O-2 as oxidising agents. The activity of the catalysts . varies with oxidising agent and the presence of surface SO42-.. NO(g) increases conversion of soot to COx-. Surface SO42- has no effect on activity for the C-(s) + O-2 reaction but decreases activity in the Carbon + NO/O-2 oxidation. This is interpreted in terms of SO42- blocking NO adsorption sites, thus poisoning the 4 NO + O-2 --> NO2 reaction, which is essential for the NOx promoted oxidation.
Type of Material
Journal Article
Publisher
Elsevier
Journal
Catalysis Communications
Volume
6
Issue
7
Start Page
472
End Page
475
Copyright (Published Version)
2005 Elsevier B.V.
Subjects

Soot combustion

Sulphate

NOx

DOI
10.1016/j.catcom.2005.04.008
Language
English
Status of Item
Peer reviewed
This item is made available under a Creative Commons License
https://creativecommons.org/licenses/by-nc-nd/3.0/ie/
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sootcomb.pdf

Size

255.66 KB

Format

Adobe PDF

Checksum (MD5)

32bf9c81dc11c41b2ae7816caaf3aadb

Owning collection
Chemistry Research Collection

Item descriptive metadata is released under a CC-0 (public domain) license: https://creativecommons.org/public-domain/cc0/.
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