Tunable single-site ruthenium catalysts for eļ¬ƒcient water oxidation

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Author(s)
Uri
Date Issued
16 June 2011
Date Available
11T15:50:23Z July 2011
Abstract
The catalytic water oxidation activity of mononuclear ruthenium complexes comprising a pyridine-functionalized abnormal triazolylidene ligand can be adjusted by modiļ¬cation of the triazolylidene substituents, which is readily achieved through click-type cycloaddition chemistry, aļ¬€ording some of the most active ruthenium catalysts known thus far for water oxidation(TONs > 400, TOFs close to 7000/h).
Sponsorship
Science Foundation Ireland
European Research Council
Other funder
Other Sponsorship
MICINN(CTQ2010-21497 and Consolider Ingenio 2010 CSD2006-0003)
Type of Material
Journal Article
Publisher
RSC publicating
Journal
Chemical Communications
Volume
2011
Issue
47
Start Page
8058
End Page
8060
Copyright (Published Version)
2011 The Royal Society of Chemistry
Keywords
Subject ā€“ LCSH
Ruthenium
Catalysts
Oxidation
DOI
Web versions
Language
English
Status of Item
Peer reviewed
This item is made available under a Creative Commons License
Owning collection
Solar Energy Conversion (SEC) Cluster Research Collection