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Synthesis and catalytic activity of histidine-based NHC ruthenium complexes
Date Issued
2011-03-28
Date Available
2015-05-25T10:52:47Z
Abstract
Main-chain C,N-protected histidine has been successfully alkylated at both side-chain nitrogens. The corresponding histidinium salt was metallated with ruthenium(II) by a transmetalation procedure, thus providing histidine-derived NHC ruthenium complexes. These bio-inspired comsxsxsplexes show appreciable activity in the catalytic transfer hydrogenation of ketones.
Sponsorship
European Research Council
Other Sponsorship
Swiss National Science Foundation
Alfred Werner Foundation
Type of Material
Journal Article
Publisher
Royal Society of Chemistry
Journal
Dalton Transactions
Volume
40
Issue
12
Start Page
2716
End Page
2719
Copyright (Published Version)
2011 The Royal Society of Chemistry
Language
English
Status of Item
Peer reviewed
This item is made available under a Creative Commons License
File(s)
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Name
DT-001768_manuscript.pdf
Size
464.01 KB
Format
Adobe PDF
Checksum (MD5)
e68f50d280c4bcd84ad6693fac16d045
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