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Rhodium-mediated activation of an alkane-type C–H bond
Author(s)
Date Issued
2010-01-14
Date Available
2012-06-14T14:22:51Z
Abstract
Abnormal C4-bonding of N-heterocyclic carbenes effectively modulates the electron density at rhodium and allows for the selective cleavage of an unactivated C(sp3)–H bond, whereas no such intramolecular C–H bond breaking is observed when the carbene binds normally through the C2 carbon.
Sponsorship
Other funder
Other Sponsorship
Swiss National Science Foundation
Sasol Ltd.
Alfred Werner Foundation
Type of Material
Journal Article
Publisher
RSC Publishing
Journal
Chemical Communications
Volume
46
Issue
2
Start Page
315
End Page
317
Copyright (Published Version)
2010 the authors
Subject – LCSH
Carbenes (Methylene compounds)
Rhodium
Activation (Chemistry)
Chemical bonds
Language
English
Status of Item
Peer reviewed
This item is made available under a Creative Commons License
File(s)
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Name
B918660c.pdf
Size
487.11 KB
Format
Adobe PDF
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64061f97309b0ef4403ecc6473311efa
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