An easy and short preparation of pentachloroacetone by selective dechlorination of hexachloroacetone under Appel conditions

Author(s)
Uri
Date Issued
2011-12
Date Available
2013-11-15T17:17:26Z
Abstract
We report a very convenient laboratory preparation of pentachloroacetone (PCA) by selective dechlorination of hexachloroacetone (HCA) via reaction with triphenylphosphine in the presence of methanol or aromatic alcohols.
Type of Material
Journal Article
Publisher
Elsevier
Journal
Tetrahedron Letters
Volume
52
Issue
52
Start Page
7113
End Page
7115
Copyright (Published Version)
2011 Elsevier Ltd.
Subjects

Hexachloroacetone

Pentachloroacetone

Triphenylphosphine

Appel reaction

Chlorophosphonium sal...

Aryloxyphosphonium sa...

DOI
Language
English
Status of Item
Peer reviewed
This item is made available under a Creative Commons License
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RajendranGilheany-PCA.pdf

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Owning collection
Chemistry Research Collection