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  5. Mesoionic triazolylidene nickel complexes: synthesis, ligand lability, and catalytic C–C bond formation activity
 
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Mesoionic triazolylidene nickel complexes: synthesis, ligand lability, and catalytic C–C bond formation activity

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Author(s)
Wei, Yingfei 
Petronilho, Ana 
Müller-Bunz, Helge 
Albrecht, Martin 
Uri
http://hdl.handle.net/10197/6826
Date Issued
28 July 2014
Date Available
19T16:37:27Z August 2015
Abstract
A set of triazolylidene (trz) nickel(II) complexes [NiCpX(trz)] was synthesized by a direct metalation of the corresponding triazolium salt with nickelocene, NiCp2. While at short reaction times and in the presence of a coordinating anion X the mono-carbene complex is preferably formed, long reaction times induce the gradual transformation of [NiCpX(trz)] to the bis-carbene complexes [Ni(Cp)(trz)2]+. Kinetic analyses lend strong support to a consecutive pathway involving triazolylidene dissociation from [NiCpX(trz)] en route to the bis-carbene complex. Similar carbene transfer is observed in a solid-state reaction upon heating the complex [NiCpI(trz)] in vacuo, which induces disproportionation to [NiI2(trz)2] and NiCp2, confirming that the Ni–C(trz) bond is kinetically labile. The complexes [Ni(Cp)(trz)2]+ and [NiCpX(trz)] were both efficient catalyst precursors for Suzuki–Miyaura cross-coupling of aryl bromides and phenylboronic acid, with turnover frequencies exceeding 228 h–1. Complex degradation after short reaction times, identified in separate experiments, prohibits high turnover numbers, and for high conversions, repetitive additions of triazolylidene nickel complex and phenylboronic acid are necessary.
Sponsorship
European Research Council
Type of Material
Journal Article
Publisher
American Chemical Society
Journal
Organometallics
Volume
33
Issue
20
Start Page
5834
End Page
5844
Copyright (Published Version)
2014 American Chemical Society
Keywords
  • Monocarbene complexes...

  • Biscarbene complexes

  • Kinetic lability

DOI
10.1021/om500593s
Language
English
Status of Item
Peer reviewed
This item is made available under a Creative Commons License
https://creativecommons.org/licenses/by-nc-nd/3.0/ie/
Owning collection
Chemistry Research Collection
Scopus© citations
47
Acquisition Date
Mar 27, 2023
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