Unprecedented Alkene Transposition in Phthalate-Amino Acid Adducts
|Title:||Unprecedented Alkene Transposition in Phthalate-Amino Acid Adducts||Authors:||Saha, Ishika; Baxendale, Ian R.; Baumann, Marcus||Permanent link:||http://hdl.handle.net/10197/12607||Date:||7-Nov-2018||Online since:||2021-11-09T16:14:27Z||Abstract:||A detailed account on the outcome of the thermal reaction between benzylidene phthalides and various amino acid derivatives is reported. It was discovered that the tricyclic pyrroles as previously described are not the products formed in these reactions. Instead under high-temperature conditions decarboxylated phthalamide adducts are formed within 5-10 minutes. Additionally, an unprecedented alkene transposition mechanism has been identified leading to the final products of these reactions.||Funding Details:||Royal Society
School of Chemistry, University College Dublin
|Type of material:||Journal Article||Publisher:||Georg Thieme||Journal:||Synlett||Volume:||29||Issue:||20||Start page:||2648||End page:||2654||Copyright (published version):||2018 Georg Thieme||Keywords:||Phthalide; Phthalamide; Tricyclic pyrrole; Alkene transposition; Polycyclic Pyrrole||DOI:||10.1055/s-0037-1611294||Language:||en||Status of Item:||Peer reviewed||ISSN:||0936-5214||This item is made available under a Creative Commons License:||https://creativecommons.org/licenses/by-nc-nd/3.0/ie/|
|Appears in Collections:||Chemistry Research Collection|
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