Unprecedented Alkene Transposition in Phthalate-Amino Acid Adducts

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Title: Unprecedented Alkene Transposition in Phthalate-Amino Acid Adducts
Authors: Saha, IshikaBaxendale, Ian R.Baumann, Marcus
Permanent link: http://hdl.handle.net/10197/12607
Date: 7-Nov-2018
Online since: 2021-11-09T16:14:27Z
Abstract: A detailed account on the outcome of the thermal reaction between benzylidene phthalides and various amino acid derivatives is reported. It was discovered that the tricyclic pyrroles as previously described are not the products formed in these reactions. Instead under high-temperature conditions decarboxylated phthalamide adducts are formed within 5-10 minutes. Additionally, an unprecedented alkene transposition mechanism has been identified leading to the final products of these reactions.
Funding Details: Royal Society
School of Chemistry, University College Dublin
Type of material: Journal Article
Publisher: Georg Thieme
Journal: Synlett
Volume: 29
Issue: 20
Start page: 2648
End page: 2654
Copyright (published version): 2018 Georg Thieme
Keywords: PhthalidePhthalamideTricyclic pyrroleAlkene transpositionPolycyclic Pyrrole
DOI: 10.1055/s-0037-1611294
Language: en
Status of Item: Peer reviewed
ISSN: 0936-5214
This item is made available under a Creative Commons License: https://creativecommons.org/licenses/by-nc-nd/3.0/ie/
Appears in Collections:Chemistry Research Collection

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