Photoinduced rearrangements in transition metal compounds

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Title: Photoinduced rearrangements in transition metal compounds
Authors: Vos, Johannes G.
Pryce, Mary T.
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Date: Nov-2010
Abstract: In this contribution a range of photo induced ligand rearrangements observed for first and second row transition metal and organometallic compounds are discussed. The processes discussed include photoinduced ligand exchange, linkage isomerisation and changes occurring within the coordination sphere of the compounds such as cis-trans and fac-mer isomerisations. The relevance of these processes for photocatalytic cycles or their application as synthetic tools is discussed where appropriate.
Funding Details: Science Foundation Ireland
Other funder
Type of material: Journal Article
Publisher: Elsevier
Copyright (published version): 2010 Elsevier B.V.
Keywords: PhotochemistryTransition metalOrganometallicIsomerisation rearrangementsPhotocatalytic
Subject LCSH: Photochemistry
Organometallic compounds
Transition metal compounds
DOI: 10.1016/j.ccr.2010.04.010
Language: en
Status of Item: Peer reviewed
Appears in Collections:Solar Energy Conversion (SEC) Cluster Research Collection

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