Tunable single-site ruthenium catalysts for efficient water oxidation

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Title: Tunable single-site ruthenium catalysts for efficient water oxidation
Authors: Bernet, Lucille
Lalrempuia, Ralte
Ghattas, Wadih
Müller-Bunz, Helge
Vigara, Laura
Llobet, Antoni
Albrecht, Martin
Permanent link: http://hdl.handle.net/10197/3010
Date: 16-Jun-2011
Abstract: The catalytic water oxidation activity of mononuclear ruthenium complexes comprising a pyridine-functionalized abnormal triazolylidene ligand can be adjusted by modification of the triazolylidene substituents, which is readily achieved through click-type cycloaddition chemistry, affording some of the most active ruthenium catalysts known thus far for water oxidation(TONs > 400, TOFs close to 7000/h).
Funding Details: Science Foundation Ireland
European Research Council
Other funder
Type of material: Journal Article
Publisher: RSC publicating
Journal: Chemical Communications
Volume: 2011
Issue: 47
Start page: 8058
End page: 8060
Copyright (published version): 2011 The Royal Society of Chemistry
Keywords: RutheniumWater oxidationCatalystSingle-site
Subject LCSH: Ruthenium
Catalysts
Oxidation
DOI: 10.1039/C1CC12615F
Other versions: http://dx.doi.org/10.1039/C1CC12615F
Language: en
Status of Item: Peer reviewed
Appears in Collections:Solar Energy Conversion (SEC) Cluster Research Collection
Chemistry Research Collection

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