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Circularly polarized lanthanide luminescence from Langmuir-Blodgett films formed from optically active and amphiphilic Eu(III) based self-assembly complexes
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| Title: | Circularly polarized lanthanide luminescence from Langmuir-Blodgett films formed from optically active and amphiphilic Eu(III) based self-assembly complexes | Authors: | Kitchen, Jonathan A.; Barry, Dawn E.; Mercs, Laszlo; Albrecht, Martin; Peacock, Robert D.; Gunnlaugsson, Thorfinnur | Permanent link: | http://hdl.handle.net/10197/3628 | Date: | 16-Jan-2012 | Online since: | 2012-06-07T16:01:51Z | Abstract: | The development of novel chiral amphiphilic self-assembled complexes 13Eu and 23Eu by using Europium(III) directed synthesis is described. These systems form stable Langmuir films at an air-water interface, which were transferred onto solid supports (quartz slides) resulting in stable monolayers that exhibit time delayed Eu(III) centered emission and circular polarized luminescence (CPL) upon excitation of the chiral naphthyl antennae. | Funding Details: | Science Foundation Ireland Irish Research Council for Science, Engineering and Technology European Research Council |
Type of material: | Journal Article | Publisher: | Wiley | Journal: | Angewandte Chemie International Edition | Volume: | 51 | Issue: | 3 | Start page: | 704 | End page: | 708 | Copyright (published version): | 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | Keywords: | Chirality; Luminescence; Lanthanide; Langmuir-Blodgett; Surface chemistry | Subject LCSH: | Chirality Thin films, Multilayered Rare earth metals Luminescence Surface chemistry |
DOI: | 10.1002/anie.201106863 | Language: | en | Status of Item: | Peer reviewed | This item is made available under a Creative Commons License: | https://creativecommons.org/licenses/by-nc-sa/1.0/ |
| Appears in Collections: | Chemistry Research Collection |
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