Circularly polarized lanthanide luminescence from Langmuir-Blodgett films formed from optically active and amphiphilic Eu(III) based self-assembly complexes

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Title: Circularly polarized lanthanide luminescence from Langmuir-Blodgett films formed from optically active and amphiphilic Eu(III) based self-assembly complexes
Authors: Kitchen, Jonathan A.Barry, Dawn E.Mercs, LaszloAlbrecht, MartinPeacock, Robert D.Gunnlaugsson, Thorfinnur
Permanent link: http://hdl.handle.net/10197/3628
Date: 16-Jan-2012
Online since: 2012-06-07T16:01:51Z
Abstract: The development of novel chiral amphiphilic self-assembled complexes 13Eu and 23Eu by using Europium(III) directed synthesis is described. These systems form stable Langmuir films at an air-water interface, which were transferred onto solid supports (quartz slides) resulting in stable monolayers that exhibit time delayed Eu(III) centered emission and circular polarized luminescence (CPL) upon excitation of the chiral naphthyl antennae.
Funding Details: Science Foundation Ireland
Irish Research Council for Science, Engineering and Technology
European Research Council
Type of material: Journal Article
Publisher: Wiley
Journal: Angewandte Chemie International Edition
Volume: 51
Issue: 3
Start page: 704
End page: 708
Copyright (published version): 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Keywords: ChiralityLuminescenceLanthanideLangmuir-BlodgettSurface chemistry
Subject LCSH: Chirality
Thin films, Multilayered
Rare earth metals
Luminescence
Surface chemistry
DOI: 10.1002/anie.201106863
Language: en
Status of Item: Peer reviewed
This item is made available under a Creative Commons License: https://creativecommons.org/licenses/by-nc-sa/1.0/
Appears in Collections:Chemistry Research Collection

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