Rhodium-mediated activation of an alkane-type C–H bond

Files in This Item:
File Description SizeFormat 
B918660c.pdf487.11 kBAdobe PDFDownload
Title: Rhodium-mediated activation of an alkane-type C–H bond
Authors: Krüger, Anneke
Neels, Antonia
Albrecht, Martin
Permanent link: http://hdl.handle.net/10197/3653
Date: 14-Jan-2010
Abstract: Abnormal C4-bonding of N-heterocyclic carbenes effectively modulates the electron density at rhodium and allows for the selective cleavage of an unactivated C(sp3)–H bond, whereas no such intramolecular C–H bond breaking is observed when the carbene binds normally through the C2 carbon.
Funding Details: Other funder
Type of material: Journal Article
Publisher: RSC Publishing
Copyright (published version): 2010 the authors
Keywords: RhodiumCH activationAbnormal carbeneC-H bond
Subject LCSH: Carbenes (Methylene compounds)
Activation (Chemistry)
Chemical bonds
DOI: 10.1039/b918660c
Language: en
Status of Item: Peer reviewed
Appears in Collections:Chemistry Research Collection

Show full item record

Citations 10

Last Week
Last month
checked on Aug 17, 2018

Page view(s) 50

checked on May 25, 2018

Download(s) 50

checked on May 25, 2018

Google ScholarTM



This item is available under the Attribution-NonCommercial-NoDerivs 3.0 Ireland. No item may be reproduced for commercial purposes. For other possible restrictions on use please refer to the publisher's URL where this is made available, or to notes contained in the item itself. Other terms may apply.