Rhodium-mediated activation of an alkane-type C–H bond
|Title:||Rhodium-mediated activation of an alkane-type C–H bond||Authors:||Krüger, Anneke
|Permanent link:||http://hdl.handle.net/10197/3653||Date:||14-Jan-2010||Abstract:||Abnormal C4-bonding of N-heterocyclic carbenes effectively modulates the electron density at rhodium and allows for the selective cleavage of an unactivated C(sp3)–H bond, whereas no such intramolecular C–H bond breaking is observed when the carbene binds normally through the C2 carbon.||Funding Details:||Other funder||Type of material:||Journal Article||Publisher:||RSC Publishing||Copyright (published version):||2010 the authors||Keywords:||Rhodium; CH activation; Abnormal carbene; C-H bond||Subject LCSH:||Carbenes (Methylene compounds)
|DOI:||10.1039/b918660c||Language:||en||Status of Item:||Peer reviewed|
|Appears in Collections:||Chemistry Research Collection|
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