A new, mild one-pot synthesis of iodinated heterocycles as suitable precursors for N-heterocyclic carbene complexes

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Title: A new, mild one-pot synthesis of iodinated heterocycles as suitable precursors for N-heterocyclic carbene complexes
Authors: Iglesias, Manuel
Schuster, Oliver
Albrecht, Martin
Permanent link: http://hdl.handle.net/10197/3686
Date: 13-Oct-2010
Abstract: The use of I2/AgOAc in dichloromethane constitutes a cheap, mild, and efficient method for the selective iodination of a variety of heterocycles. In a number of cases, this method provides superior yields than other literature methods and affords iodo-functionalized heterocycles that are suitable precursors for carbene complexes.
Funding Details: European Research Council
Type of material: Journal Article
Publisher: Elsevier
Copyright (published version): 2010 Elsevier
Keywords: Iodination;Imidazole;N-heterocyclic carbene;Oxidative addition;Ligand precursors;Abnormal carbene complexes
Subject LCSH: Heterocyclic compounds
Imidazoles
Carbenes (Methylene compounds)
DOI: 10.1016/j.tetlet.2010.07.178
Language: en
Status of Item: Peer reviewed
Appears in Collections:Chemistry Research Collection

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