Expanding the family of mesoionic complexes: donor properties and catalytic impact of palladated isoxazolylidenes
|Title:||Expanding the family of mesoionic complexes: donor properties and catalytic impact of palladated isoxazolylidenes||Authors:||Iglesias, Manuel; Albrecht, Martin||Permanent link:||http://hdl.handle.net/10197/3709||Date:||2010||Online since:||2012-06-28T16:18:15Z||Abstract:||Abnormal isoxazolylidene complexes, a new subclass of mesoionic complexes containing an isoxazolium-derived carbene type ligand, have been synthesised via oxidative addition and compared to structurally related mesoionic complexes by using 31P NMR spectroscopy as a convenient probe for their donor ability and in catalytic cross-coupling reactions.||Funding Details:||European Research Council||metadata.dc.description.othersponsorship:||COST D40
Swiss National Science Foundation
|Type of material:||Journal Article||Publisher:||RSC Publishing||Journal:||Dalton Transactions||Volume:||39||Issue:||22||Start page:||5213||End page:||5215||Copyright (published version):||The Royal Society of Chemistry 2010||Keywords:||Abnormal carbene; Isoxazolylidene; Palladium; Donor properties; Cross-coupling catalysis||Subject LCSH:||Carbenes (Methylene compounds)
|DOI:||10.1039/C0DT00027B||Language:||en||Status of Item:||Peer reviewed|
|Appears in Collections:||Chemistry Research Collection|
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