Non-classical N-Heterocyclic carbene complexes
|Title:||Non-classical N-Heterocyclic carbene complexes||Authors:||Krüger, Anneke
|Permanent link:||http://hdl.handle.net/10197/3735||Date:||2010||Abstract:||The expansion of the concept of N-heterocyclic carbenes as ligands for transition metals to mesoionic ligand systems has led to the discovery of a wide range of non-classical carbene-type ligands. These non-classical carbene-type ligands are characterised by a significantly lower heteroatom stabilisation of the (putative) free carbene, a situation that also affects the ligand donor properties and hence the reactivity of the coordinated metal centre. Based on the unique impact of non-classical carbene-type ligands, a number of attractive transition metal-catalysed processes have been disclosed in recent years, predominantly in the area of cross-coupling reactions, hydrogenations, and olefin metathesis||Funding Details:||Not applicable||Type of material:||Book Chapter||Publisher:||RSC Publishing||Copyright (published version):||2011 Royal Society of Chemistry||Keywords:||N-heterocyclic carbenes;Abnormal carbenes;Catalysis;Review||Subject LCSH:||Carbenes (Methylene compounds)
|DOI:||10.1039/9781849732161-00134||Language:||en||Status of Item:||Peer reviewed||Is part of:||S. Diez-Gonzalez (ed): N-heterocyclic carbenes: From Laboratory Curiosities to Efficient Synthetic Tools|
|Appears in Collections:||Chemistry Research Collection|
Show full item record
This item is available under the Attribution-NonCommercial-NoDerivs 3.0 Ireland. No item may be reproduced for commercial purposes. For other possible restrictions on use please refer to the publisher's URL where this is made available, or to notes contained in the item itself. Other terms may apply.