Non-classical N-Heterocyclic carbene complexes
|Title:||Non-classical N-Heterocyclic carbene complexes||Authors:||Krüger, Anneke
|Permanent link:||http://hdl.handle.net/10197/3735||Date:||2010||Online since:||2012-08-10T14:01:42Z||Abstract:||The expansion of the concept of N-heterocyclic carbenes as ligands for transition metals to mesoionic ligand systems has led to the discovery of a wide range of non-classical carbene-type ligands. These non-classical carbene-type ligands are characterised by a significantly lower heteroatom stabilisation of the (putative) free carbene, a situation that also affects the ligand donor properties and hence the reactivity of the coordinated metal centre. Based on the unique impact of non-classical carbene-type ligands, a number of attractive transition metal-catalysed processes have been disclosed in recent years, predominantly in the area of cross-coupling reactions, hydrogenations, and olefin metathesis||Funding Details:||Not applicable||Type of material:||Book Chapter||Publisher:||RSC Publishing||Copyright (published version):||2011 Royal Society of Chemistry||Keywords:||N-heterocyclic carbenes; Abnormal carbenes; Catalysis; Review||Subject LCSH:||Carbenes (Methylene compounds)
|DOI:||10.1039/9781849732161-00134||Language:||en||Status of Item:||Peer reviewed||Is part of:||S. Diez-Gonzalez (ed): N-heterocyclic carbenes: From Laboratory Curiosities to Efficient Synthetic Tools||ISBN:||978-1-84973-216-1|
|Appears in Collections:||Chemistry Research Collection|
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