An easy and short preparation of pentachloroacetone by selective dechlorination of hexachloroacetone under Appel conditions

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Title: An easy and short preparation of pentachloroacetone by selective dechlorination of hexachloroacetone under Appel conditions
Authors: Rajendran, Kamalraj V.
Carr, Damien J.
Gilheany, Declan G.
Permanent link: http://hdl.handle.net/10197/4932
Date: Dec-2011
Online since: 2013-11-15T17:17:26Z
Abstract: We report a very convenient laboratory preparation of pentachloroacetone (PCA) by selective dechlorination of hexachloroacetone (HCA) via reaction with triphenylphosphine in the presence of methanol or aromatic alcohols.
Type of material: Journal Article
Publisher: Elsevier
Journal: Tetrahedron Letters
Volume: 52
Issue: 52
Start page: 7113
End page: 7115
Copyright (published version): 2011 Elsevier Ltd.
Keywords: HexachloroacetonePentachloroacetoneTriphenylphosphineAppel reactionChlorophosphonium saltAryloxyphosphonium salt
DOI: 10.1016/j.tetlet.2011.10.101
Language: en
Status of Item: Peer reviewed
Appears in Collections:Chemistry Research Collection

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