Simple unprecedented conversion of phosphine oxides and sulfides to phosphine boranes using sodium borohydride
|Title:||Simple unprecedented conversion of phosphine oxides and sulfides to phosphine boranes using sodium borohydride||Authors:||Rajendran, Kamalraj V.; Gilheany, Declan G.||Permanent link:||http://hdl.handle.net/10197/4933||Date:||Feb-2012||Online since:||2013-11-15T17:20:38Z||Abstract:||A variety of phosphine oxides and sulfides can be efficiently converted directly to the corresponding phosphine boranes using oxalyl chloride followed by sodium borohydride. Optically active P-stereogenic phosphine oxides can be converted stereospecifically to phosphine boranes with inversion of configuration by treatment with Meerwein's salt followed by sodium borohydride.||Funding Details:||Science Foundation Ireland
|Funding Details:||University College Dublin for a President’s Research Fellowship||Type of material:||Journal Article||Publisher:||RSC Publishing||Journal:||Chemical Communications||Volume:||48||Issue:||6||Start page:||817||End page:||819||Copyright (published version):||The Royal Society of Chemistry 2012||Keywords:||Oxalyl chloride; P-stereogenic phosphine oxides; Meerwein’s salt; Phosphorous chemistry||DOI:||10.1039/C1CC14856G||Language:||en||Status of Item:||Peer reviewed||This item is made available under a Creative Commons License:||https://creativecommons.org/licenses/by-nc-nd/3.0/ie/|
|Appears in Collections:||Chemistry Research Collection|
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