Simple unprecedented conversion of phosphine oxides and sulfides to phosphine boranes using sodium borohydride
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|Title:||Simple unprecedented conversion of phosphine oxides and sulfides to phosphine boranes using sodium borohydride||Authors:||Rajendran, Kamalraj V.
Gilheany, Declan G.
|Permanent link:||http://hdl.handle.net/10197/4933||Date:||Feb-2012||Abstract:||A variety of phosphine oxides and sulfides can be efficiently converted directly to the corresponding phosphine boranes using oxalyl chloride followed by sodium borohydride. Optically active P-stereogenic phosphine oxides can be converted stereospecifically to phosphine boranes with inversion of configuration by treatment with Meerwein's salt followed by sodium borohydride.||Funding Details:||Science Foundation Ireland
|Type of material:||Journal Article||Publisher:||RSC Publishing||Copyright (published version):||The Royal Society of Chemistry 2012||Keywords:||Oxalyl chloride;P-stereogenic phosphine oxides;Meerwein’s salt;Phosphorous chemistry||DOI:||10.1039/C1CC14856G||Language:||en||Status of Item:||Peer reviewed|
|Appears in Collections:||Chemistry Research Collection|
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