Simple unprecedented conversion of phosphine oxides and sulfides to phosphine boranes using sodium borohydride

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Title: Simple unprecedented conversion of phosphine oxides and sulfides to phosphine boranes using sodium borohydride
Authors: Rajendran, Kamalraj V.
Gilheany, Declan G.
Permanent link: http://hdl.handle.net/10197/4933
Date: Feb-2012
Abstract: A variety of phosphine oxides and sulfides can be efficiently converted directly to the corresponding phosphine boranes using oxalyl chloride followed by sodium borohydride. Optically active P-stereogenic phosphine oxides can be converted stereospecifically to phosphine boranes with inversion of configuration by treatment with Meerwein's salt followed by sodium borohydride.
Funding Details: Science Foundation Ireland
Other funder
Type of material: Journal Article
Publisher: RSC Publishing
Copyright (published version): The Royal Society of Chemistry 2012
Keywords: Oxalyl chloride;P-stereogenic phosphine oxides;Meerwein’s salt;Phosphorous chemistry
DOI: 10.1039/C1CC14856G
Language: en
Status of Item: Peer reviewed
Appears in Collections:Chemistry Research Collection

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