Simple unprecedented conversion of phosphine oxides and sulfides to phosphine boranes using sodium borohydride

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Title: Simple unprecedented conversion of phosphine oxides and sulfides to phosphine boranes using sodium borohydride
Authors: Rajendran, Kamalraj V.Gilheany, Declan G.
Permanent link: http://hdl.handle.net/10197/4933
Date: Feb-2012
Online since: 2013-11-15T17:20:38Z
Abstract: A variety of phosphine oxides and sulfides can be efficiently converted directly to the corresponding phosphine boranes using oxalyl chloride followed by sodium borohydride. Optically active P-stereogenic phosphine oxides can be converted stereospecifically to phosphine boranes with inversion of configuration by treatment with Meerwein's salt followed by sodium borohydride.
Funding Details: Science Foundation Ireland
Other funder
Funding Details: University College Dublin for a President’s Research Fellowship
Type of material: Journal Article
Publisher: RSC Publishing
Journal: Chemical Communications
Volume: 48
Issue: 6
Start page: 817
End page: 819
Copyright (published version): The Royal Society of Chemistry 2012
Keywords: Oxalyl chlorideP-stereogenic phosphine oxidesMeerwein’s saltPhosphorous chemistry
DOI: 10.1039/C1CC14856G
Language: en
Status of Item: Peer reviewed
This item is made available under a Creative Commons License: https://creativecommons.org/licenses/by-nc-nd/3.0/ie/
Appears in Collections:Chemistry Research Collection

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