A convenient and mild chromatography-free method for the purification of the products of Wittig and Appel reactions
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|Title:||A convenient and mild chromatography-free method for the purification of the products of Wittig and Appel reactions||Authors:||Byrne, Peter A.
Rajendran, Kamalraj V.
Gilheany, Declan G.
|Permanent link:||http://hdl.handle.net/10197/4940||Date:||Mar-2012||Abstract:||A mild method for the facile removal of phosphine oxide from the crude products of Wittig and Appel reactions is described. Work-up with oxalyl chloride to generate insol. chlorophosphonium salt (CPS) yields phosphorus-free products for a wide variety of these reactions. The CPS product can be further converted into phosphine.||Type of material:||Journal Article||Publisher:||RSC Publishing||Copyright (published version):||Royal Society of Chemistry 2012||Keywords:||Wittig and appel reactions||DOI:||10.1039/C2OB07074J||Language:||en||Status of Item:||Peer reviewed|
|Appears in Collections:||Chemistry Research Collection|
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