Characterisation of spruce, salix, miscanthus and wheat straw for pyrolysis applications

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Title: Characterisation of spruce, salix, miscanthus and wheat straw for pyrolysis applications
Authors: Butler, Eoin
Devlin, Ger
Meier, Dietrich
McDonnell, Kevin
Permanent link: http://hdl.handle.net/10197/5974
Date: Mar-2013
Abstract: This research details the characterisation of four Irish-grown lignocellulosic biomasses for pyrolysis by biomass composition analysis, TGA, and Py-GC/MS-FID. Ash content (mf) increased in the order spruce (0.26 wt.%) < salix (1.16 wt.%) < miscanthus (3.43 wt.%) < wheat straw (3.76 wt.%). Analysis of hydrolysis-derived sugar monomers showed that xylose concentrations (4.69–26.76 wt.%) ranged significantly compared to glucose concentrations (40.98–49.82 wt.%). Higher hemicellulose and ash contents probably increased non-volatile matter, and decreased the temperature of maximum degradation by TGA as well as yields of GC-detectable compounds by Py-GC/MS-FID. Differences in composition and degradation were reflected in the pyrolysate composition by lower quantities of sugars (principally levoglucosan), pyrans, and furans for salix, miscanthus, and wheat straw compared to spruce, and increased concentrations of cyclopentenones and acids.
Funding Details: Science Foundation Ireland
Type of material: Journal Article
Publisher: Elsevier
Copyright (published version): 2012 Elsevier
Keywords: Pyrolysis;Biomass;Py-GC/MS;Thermogravimetry;Biofuel;HPAEC;Fast pyrolysis
DOI: 10.1016/j.biortech.2012.12.013
Language: en
Status of Item: Peer reviewed
Appears in Collections:Biosystems and Food Engineering Research Collection

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