Bimetallic Iridium-Carbene Complexes with Mesoionic Triazolylidene Ligands for Water Oxidation Catalysis

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Title: Bimetallic Iridium-Carbene Complexes with Mesoionic Triazolylidene Ligands for Water Oxidation Catalysis
Authors: Petronilho, AnaWoods, James A.Bernhard, StefanAlbrecht, Martin
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Date: Feb-2014
Online since: 2015-05-15T15:50:23Z
Abstract: Two new diiridium–triazolylidene complexes were prepared as bimetallic analogues of established mononuclear water oxidation catalysts. Both complexes are efficient catalyst precursors in the presence of cerium ammonium nitrate (CAN) as sacrificial oxidant. Up to 20000:1 ratios of CAN/complex, the turnover limitation is the availability of CAN and not the catalyst stability. The water oxidation activity of the bimetallic complexes is not better than the monometallic species at 0.6 mm catalyst concentration. Under dilute conditions (0.03 mm), the bimetallic complexes double their activity, whereas the monometallic complexes show an opposite trend and display markedly reduced rates, thereby suggesting a benefit of the close proximity of two metal centers in this low concentration regime. The high dependence of catalyst activity on reaction conditions indicates that caution is required when catalysts are compared by their turnover frequencies only.
Funding Details: European Research Council
Science Foundation Ireland
metadata.dc.description.othersponsorship: National Science Foundation
Type of material: Journal Article
Publisher: Wiley
Journal: European Journal of Inorganic Chemistry
Volume: 2014
Issue: 4
Start page: 708
End page: 714
Copyright (published version): 2014 Wiley
Keywords: Water chemistryOxidationIridiumCarbenesBimetallic complexesN-heterocyclic carbeneTriazolylideneWater oxidationBimetallic
DOI: 10.1002/ejic.201300843
Language: en
Status of Item: Peer reviewed
Appears in Collections:Chemistry Research Collection

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