Synthesis and catalytic activity of histidine-based NHC ruthenium complexes
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Title: | Synthesis and catalytic activity of histidine-based NHC ruthenium complexes | Authors: | Monney, Angèle Venkatachalam, Galmari Albrecht, Martin |
Permanent link: | http://hdl.handle.net/10197/6599 | Date: | 28-Mar-2011 | Online since: | 2015-05-25T10:52:47Z | Abstract: | Main-chain C,N-protected histidine has been successfully alkylated at both side-chain nitrogens. The corresponding histidinium salt was metallated with ruthenium(II) by a transmetalation procedure, thus providing histidine-derived NHC ruthenium complexes. These bio-inspired comsxsxsplexes show appreciable activity in the catalytic transfer hydrogenation of ketones. | Funding Details: | European Research Council | Type of material: | Journal Article | Publisher: | Royal Society of Chemistry | Journal: | Dalton Transactions | Volume: | 40 | Issue: | 12 | Start page: | 2716 | End page: | 2719 | Copyright (published version): | 2011 The Royal Society of Chemistry | Keywords: | Heterocyclic carbene complexes; Transition-metal-complexes; Bioorganometallic chemistry; Amino-acids; Transfer hydrogenation; Asymmetric catalysis; Structural diversity; Directed evolution; Ligands; Reactivity | DOI: | 10.1039/c0dt01768j | Language: | en | Status of Item: | Peer reviewed |
Appears in Collections: | Chemistry Research Collection |
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