Synthesis and catalytic activity of histidine-based NHC ruthenium complexes
|Title:||Synthesis and catalytic activity of histidine-based NHC ruthenium complexes||Authors:||Monney, Angèle
|Permanent link:||http://hdl.handle.net/10197/6599||Date:||28-Mar-2011||Online since:||2015-05-25T10:52:47Z||Abstract:||Main-chain C,N-protected histidine has been successfully alkylated at both side-chain nitrogens. The corresponding histidinium salt was metallated with ruthenium(II) by a transmetalation procedure, thus providing histidine-derived NHC ruthenium complexes. These bio-inspired comsxsxsplexes show appreciable activity in the catalytic transfer hydrogenation of ketones.||Funding Details:||European Research Council||Type of material:||Journal Article||Publisher:||Royal Society of Chemistry||Journal:||Dalton Transactions||Volume:||40||Issue:||12||Start page:||2716||End page:||2719||Copyright (published version):||2011 The Royal Society of Chemistry||Keywords:||Heterocyclic carbene complexes; Transition-metal-complexes; Bioorganometallic chemistry; Amino-acids; Transfer hydrogenation; Asymmetric catalysis; Structural diversity; Directed evolution; Ligands; Reactivity||DOI:||10.1039/c0dt01768j||Language:||en||Status of Item:||Peer reviewed|
|Appears in Collections:||Chemistry Research Collection|
Show full item record
Page view(s) 5076
This item is available under the Attribution-NonCommercial-NoDerivs 3.0 Ireland. No item may be reproduced for commercial purposes. For other possible restrictions on use please refer to the publisher's URL where this is made available, or to notes contained in the item itself. Other terms may apply.