Synthesis and catalytic activity of histidine-based NHC ruthenium complexes

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Title: Synthesis and catalytic activity of histidine-based NHC ruthenium complexes
Authors: Monney, Angèle
Venkatachalam, Galmari
Albrecht, Martin
Permanent link: http://hdl.handle.net/10197/6599
Date: 28-Mar-2011
Abstract: Main-chain C,N-protected histidine has been successfully alkylated at both side-chain nitrogens. The corresponding histidinium salt was metallated with ruthenium(II) by a transmetalation procedure, thus providing histidine-derived NHC ruthenium complexes. These bio-inspired comsxsxsplexes show appreciable activity in the catalytic transfer hydrogenation of ketones.
Funding Details: European Research Council
Type of material: Journal Article
Publisher: Royal Society of Chemistry
Copyright (published version): 2011 The Royal Society of Chemistry
Keywords: Heterocyclic carbene complexes;Transition-metal-complexes;Bioorganometallic chemistry;Amino-acids;Transfer hydrogenation;Asymmetric catalysis;Structural diversity;Directed evolution;Ligands;Reactivity
DOI: 10.1039/c0dt01768j
Language: en
Status of Item: Peer reviewed
Appears in Collections:Chemistry Research Collection

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