Synthesis and catalytic activity of histidine-based NHC ruthenium complexes
|Title:||Synthesis and catalytic activity of histidine-based NHC ruthenium complexes||Authors:||Monney, Angèle
|Permanent link:||http://hdl.handle.net/10197/6599||Date:||28-Mar-2011||Abstract:||Main-chain C,N-protected histidine has been successfully alkylated at both side-chain nitrogens. The corresponding histidinium salt was metallated with ruthenium(II) by a transmetalation procedure, thus providing histidine-derived NHC ruthenium complexes. These bio-inspired comsxsxsplexes show appreciable activity in the catalytic transfer hydrogenation of ketones.||Funding Details:||European Research Council||Type of material:||Journal Article||Publisher:||Royal Society of Chemistry||Copyright (published version):||2011 The Royal Society of Chemistry||Keywords:||Heterocyclic carbene complexes;Transition-metal-complexes;Bioorganometallic chemistry;Amino-acids;Transfer hydrogenation;Asymmetric catalysis;Structural diversity;Directed evolution;Ligands;Reactivity||DOI:||10.1039/c0dt01768j||Language:||en||Status of Item:||Peer reviewed|
|Appears in Collections:||Chemistry Research Collection|
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