Mesoionic oxides: facile access from triazolium salts or triazolylidene copper precursors and, catalytic relevance

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Title: Mesoionic oxides: facile access from triazolium salts or triazolylidene copper precursors and, catalytic relevance
Authors: Petronilho, AnaMüller-Bunz, HelgeAlbrecht, Martin
Permanent link: http://hdl.handle.net/10197/6605
Date: 4-Jul-2012
Online since: 2015-06-16T13:52:56Z
Abstract: Reaction of CsOH with triazolium salts affords mesoionic compounds containing an exocyclic oxygen; the same product is obtained by reaction of the corresponding Cu(I) triazolylidenes with CsOH and represents an unusual reactivity pattern of N-heterocyclic carbene precursors that has implications for carbene copper-catalyzed reactions.
Funding Details: European Research Council
Science Foundation Ireland
Type of material: Journal Article
Publisher: Royal Society of Chemistry
Journal: Chemical Communications
Volume: 48
Issue: 52
Start page: 6499
End page: 6501
Copyright (published version): 2012 The Royal Society of Chemistry
Keywords: CatalysisCopperSynthetic methodology
DOI: 10.1039/C2CC32843G
Language: en
Status of Item: Peer reviewed
Appears in Collections:Chemistry Research Collection

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