Dinuclear ruthenium complexes containing a new ditopic phthalazin- bis(triazole) ligand that promotes metal-metal interactions

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Title: Dinuclear ruthenium complexes containing a new ditopic phthalazin- bis(triazole) ligand that promotes metal-metal interactions
Authors: Aguiló, JoanNaeimi, AtenaBofill, RogerMüller-Bunz, HelgeAlbrecht, Martinet al.
Permanent link: http://hdl.handle.net/10197/6608
Date: 1-May-2014
Online since: 2015-06-17T08:30:23Z
Abstract: Much attention has been paid to heterocyclic N-containing ligands due to their applicability as bridging ligands in the synthesis of redox active dinuclear metal complexes. With this aim, we report the synthesis and full characterization of a novel phthalazine-triazole ligand (1,4-bis(1-methyl-1H-1, 2,3-triazol-4-yl)phthalazine). Moreover, we show that the phthalazine nitrogen atoms of this N-heterocyclic ligand are more reactive towards alkylating agents than the triazole groups. New ruthenium (ii) complexes containing this ligand have been obtained and characterized both structurally and electrochemically. The geometry imposed by the ligand allows the placement of two ruthenium centers in very close proximity so that efficient through-space interactions take place, a concept of crucial importance for electron transfer processes.
Funding Details: Science Foundation Ireland
metadata.dc.description.othersponsorship: MINECO
Type of material: Journal Article
Publisher: Royal Society of Chemistry
Journal: New Journal of Chemistry
Volume: 38
Issue: 5
Start page: 1980
End page: 1987
Copyright (published version): 2014 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique
Keywords: Ligand synthesisSonogashira cross-coupling reactionMultimetallic systemsTriazolium salts
DOI: 10.1039/c3nj01209c
Language: en
Status of Item: Peer reviewed
Appears in Collections:Chemistry Research Collection

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