Dinuclear ruthenium complexes containing a new ditopic phthalazin- bis(triazole) ligand that promotes metal-metal interactions
|Title:||Dinuclear ruthenium complexes containing a new ditopic phthalazin- bis(triazole) ligand that promotes metal-metal interactions||Authors:||Aguiló, Joan; Naeimi, Atena; Bofill, Roger; Müller-Bunz, Helge; Albrecht, Martin; et al.||Permanent link:||http://hdl.handle.net/10197/6608||Date:||1-May-2014||Online since:||2015-06-17T08:30:23Z||Abstract:||Much attention has been paid to heterocyclic N-containing ligands due to their applicability as bridging ligands in the synthesis of redox active dinuclear metal complexes. With this aim, we report the synthesis and full characterization of a novel phthalazine-triazole ligand (1,4-bis(1-methyl-1H-1, 2,3-triazol-4-yl)phthalazine). Moreover, we show that the phthalazine nitrogen atoms of this N-heterocyclic ligand are more reactive towards alkylating agents than the triazole groups. New ruthenium (ii) complexes containing this ligand have been obtained and characterized both structurally and electrochemically. The geometry imposed by the ligand allows the placement of two ruthenium centers in very close proximity so that efficient through-space interactions take place, a concept of crucial importance for electron transfer processes.||Funding Details:||Science Foundation Ireland||metadata.dc.description.othersponsorship:||MINECO||Type of material:||Journal Article||Publisher:||Royal Society of Chemistry||Journal:||New Journal of Chemistry||Volume:||38||Issue:||5||Start page:||1980||End page:||1987||Copyright (published version):||2014 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique||Keywords:||Ligand synthesis; Sonogashira cross-coupling reaction; Multimetallic systems; Triazolium salts||DOI:||10.1039/c3nj01209c||Language:||en||Status of Item:||Peer reviewed|
|Appears in Collections:||Chemistry Research Collection|
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