Springloaded porphyrin NHC hybrid rhodium(III) complexes: carbene dissociation and oxidation catalysis

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Title: Springloaded porphyrin NHC hybrid rhodium(III) complexes: carbene dissociation and oxidation catalysis
Authors: Olguín, Juan
Müller-Bunz, Helge
Albrecht, Martin
Permanent link: http://hdl.handle.net/10197/6719
Date: 4-Feb-2014
Abstract: Porphyrin rhodium(III) complexes accommodate one or two NHC ligands in the apical position, which leads to severe porphyrin distortion and dearomatization. The strain in the bis(carbene) complex induces facile carbene dissociation and the formation of a catalytically active site for alcohol oxidation.
Funding Details: European Research Council
Irish Research Council
Science Foundation Ireland
Type of material: Journal Article
Publisher: Royal Society of Chemistry
Copyright (published version): 2012 The Royal Society of Chemistry
Keywords: Rhodium porphyrin synthons;Porphyrin distortion;Dearomatization;Alcohol oxidation;Catalysis
DOI: 10.1039/C4CC00497C
Language: en
Status of Item: Peer reviewed
Appears in Collections:Chemistry Research Collection

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