Synthesis of a sterically modulated pyridine-NHC palladium complex and its reactivity towards ethylene
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|Title:||Synthesis of a sterically modulated pyridine-NHC palladium complex and its reactivity towards ethylene||Authors:||Khlebnikov, Vsevolod
|Permanent link:||http://hdl.handle.net/10197/6820||Date:||1-Aug-2012||Abstract:||A new cationic pyridine-carbene palladium complex has been prepared that features a C,N-bidentate coordinating ligand with a shielded pyridine and a sterically less protected carbene moiety; evaluation of this complex in ethylene polymerization revealed competitive reductive elimination processes and provides guidelines for further catalyst design.||Funding Details:||University College Dublin||Type of material:||Journal Article||Publisher:||Royal Society of Chemistry||Journal:||New Journal of Chemistry||Volume:||36||Issue:||8||Start page:||1552||End page:||1555||Copyright (published version):||2012 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique||Keywords:||N-heterocyclic carbenes; Late transition metal complexes; Catalyst precursors; Polymerization reactions||DOI:||10.1039/C2NJ40287D||Language:||en||Status of Item:||Peer reviewed|
|Appears in Collections:||Chemistry Research Collection|
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