Synthesis of a sterically modulated pyridine-NHC palladium complex and its reactivity towards ethylene

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Title: Synthesis of a sterically modulated pyridine-NHC palladium complex and its reactivity towards ethylene
Authors: Khlebnikov, Vsevolod
Meduri, Angelo
Müller-Bunz, Helge
Milani, Barbara
Albrecht, Martin
Permanent link: http://hdl.handle.net/10197/6820
Date: 1-Aug-2012
Abstract: A new cationic pyridine-carbene palladium complex has been prepared that features a C,N-bidentate coordinating ligand with a shielded pyridine and a sterically less protected carbene moiety; evaluation of this complex in ethylene polymerization revealed competitive reductive elimination processes and provides guidelines for further catalyst design.
Funding Details: University College Dublin
Type of material: Journal Article
Publisher: Royal Society of Chemistry
Journal: New Journal of Chemistry
Volume: 36
Issue: 8
Start page: 1552
End page: 1555
Copyright (published version): 2012 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique
Keywords: N-heterocyclic carbenesLate transition metal complexesCatalyst precursorsPolymerization reactions
DOI: 10.1039/C2NJ40287D
Language: en
Status of Item: Peer reviewed
Appears in Collections:Chemistry Research Collection

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