A chelating tetrapeptide rhodium complex comprised of a histidylidene residue: biochemical tailoring of a NHC-Rh hydrosilylation catalyst

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Title: A chelating tetrapeptide rhodium complex comprised of a histidylidene residue: biochemical tailoring of a NHC-Rh hydrosilylation catalyst
Authors: Monney, Angèle
Albrecht, Martin
Permanent link: http://hdl.handle.net/10197/6822
Date: 15-Oct-2012
Abstract: Coupling of a histidinium salt with a MetAlaAla amino acid sequence followed by metallation with [RhCl(cod)]2 yields a rhodium(I) NHC complex with a pending peptide residue. Methionine chelation, induced by chloride abstraction from the metal coordination sphere, affords an efficient hydrosilylation catalyst precursor comprised of a peptidic macrocyclic chelate backbone.
Funding Details: European Research Council
Type of material: Journal Article
Publisher: Royal Society of Chemistry
Copyright (published version): 2012 The Royal Society of Chemistry
Keywords: Organometallic entities;Bioorganometallic chemistry
DOI: 10.1039/C2CC35491H
Language: en
Status of Item: Peer reviewed
Appears in Collections:Chemistry Research Collection

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