A chelating tetrapeptide rhodium complex comprised of a histidylidene residue: biochemical tailoring of a NHC-Rh hydrosilylation catalyst

DC FieldValueLanguage
dc.contributor.authorMonney, Angèle-
dc.contributor.authorAlbrecht, Martin-
dc.date.accessioned2015-08-19T16:09:07Z-
dc.date.available2015-08-19T16:09:07Z-
dc.date.copyright2012 The Royal Society of Chemistryen
dc.date.issued2012-10-15-
dc.identifier.citationChemical Communicationsen
dc.identifier.urihttp://hdl.handle.net/10197/6822-
dc.description.abstractCoupling of a histidinium salt with a MetAlaAla amino acid sequence followed by metallation with [RhCl(cod)]2 yields a rhodium(I) NHC complex with a pending peptide residue. Methionine chelation, induced by chloride abstraction from the metal coordination sphere, affords an efficient hydrosilylation catalyst precursor comprised of a peptidic macrocyclic chelate backbone.en
dc.description.sponsorshipEuropean Research Councilen
dc.language.isoenen
dc.publisherRoyal Society of Chemistryen
dc.subjectOrganometallic entitiesen
dc.subjectBioorganometallic chemistryen
dc.titleA chelating tetrapeptide rhodium complex comprised of a histidylidene residue: biochemical tailoring of a NHC-Rh hydrosilylation catalysten
dc.typeJournal Articleen
dc.internal.authorcontactothermartin.albrecht@ucd.ie-
dc.statusPeer revieweden
dc.identifier.volume48en
dc.identifier.issue89en
dc.identifier.startpage10960en
dc.identifier.endpage10962en
dc.identifier.doi10.1039/C2CC35491H-
dc.neeo.contributorMonney|Angèle|aut|-
dc.neeo.contributorAlbrecht|Martin|aut|-
dc.description.othersponsorshipSwiss National Science Foundationen
dc.internal.rmsid314322185-
dc.date.updated2015-05-12T13:56:17Z-
item.grantfulltextopen-
item.fulltextWith Fulltext-
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