Transfer hydrogenation of unfunctionalised alkenes using N-heterocyclic carbene ruthenium catalyst precursors

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Title: Transfer hydrogenation of unfunctionalised alkenes using N-heterocyclic carbene ruthenium catalyst precursors
Authors: Horn, Sabine
Albrecht, Martin
Permanent link: http://hdl.handle.net/10197/6833
Date: 21-Aug-2011
Abstract: Transfer hydrogenation of unfunctionalised and aliphatic alkenes in iPrOH/KOH is efficiently catalysed by an olefin-tethered N-heterocyclic carbene ruthenium complex, which also catalyses double bond migration as a competitive and considerably faster process.
Funding Details: European Research Council
Type of material: Journal Article
Publisher: Royal Society of Chemistry
Copyright (published version): 2011 The Royal Society of Chemistry
Keywords: Asymmetric transfer hydrogenation;Heterogeneous catalysis;Homogeneous catalysis;Mechanistic aspects;Carbonyl-compounds;Iridium complexes;Metal-complexes;Ligands;Reactivity;Alcohols
DOI: 10.1039/c1cc12923f
Language: en
Status of Item: Peer reviewed
Appears in Collections:Chemistry Research Collection

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