Transfer hydrogenation of unfunctionalised alkenes using N-heterocyclic carbene ruthenium catalyst precursors
|Title:||Transfer hydrogenation of unfunctionalised alkenes using N-heterocyclic carbene ruthenium catalyst precursors||Authors:||Horn, Sabine
|Permanent link:||http://hdl.handle.net/10197/6833||Date:||21-Aug-2011||Online since:||2015-08-21T16:07:12Z||Abstract:||Transfer hydrogenation of unfunctionalised and aliphatic alkenes in iPrOH/KOH is efficiently catalysed by an olefin-tethered N-heterocyclic carbene ruthenium complex, which also catalyses double bond migration as a competitive and considerably faster process.||Funding Details:||European Research Council||Type of material:||Journal Article||Publisher:||Royal Society of Chemistry||Journal:||Chemical Communications||Volume:||47||Issue:||31||Start page:||8802||End page:||8804||Copyright (published version):||2011 The Royal Society of Chemistry||Keywords:||Asymmetric transfer hydrogenation; Heterogeneous catalysis; Homogeneous catalysis; Mechanistic aspects; Carbonyl-compounds; Iridium complexes; Metal-complexes; Ligands; Reactivity; Alcohols||DOI:||10.1039/c1cc12923f||Language:||en||Status of Item:||Peer reviewed|
|Appears in Collections:||Chemistry Research Collection|
Show full item record
This item is available under the Attribution-NonCommercial-NoDerivs 3.0 Ireland. No item may be reproduced for commercial purposes. For other possible restrictions on use please refer to the publisher's URL where this is made available, or to notes contained in the item itself. Other terms may apply.