A Bridge Too Far: Testing the Limits of Polypyridyl Ligands in Bridging Soluble Subunits of a Coordination Polymer

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Title: A Bridge Too Far: Testing the Limits of Polypyridyl Ligands in Bridging Soluble Subunits of a Coordination Polymer
Authors: Beddoe, Samuel V. F.Fitzpatrick, Anthony J.Price, Jason R.Morgan, Grace G.Keene, Tony D.et al.
Permanent link: http://hdl.handle.net/10197/9826
Date: 3-Nov-2017
Online since: 2019-04-08T07:50:12Z
Abstract: Starting with a coordination polymer, {[Cu(L)]2}n (1 where H2L = salicylidene-2-aminophenol), we have explored the ability of polypyridyl ligands (P) to bridge the monomer complex to form nine {[Cu(L)]2(P)} complexes. The identity and solution stability of the [Cu(L)] units has been investigated through a novel combined UV-vis/EPR experiment and it has been found to be a stable supramolecular building unit for the construction of discrete complexes and coordination polymers. The reorganization of [Cu(L)] units to a new coordination polymer on addition of 4, 4′- bipyridine markedly changes the connectivity of the structure and the magnitude of the antiferromagnetic interactions through reorientation of the Cu(II) orbitals. We also present the structure of 1, 80 years after its synthesis was first reported.
Funding Details: European Commission - Seventh Framework Programme (FP7)
Science Foundation Ireland
University College Dublin
Funding Details: Worldwide Universities Network Global Partnership Fund award
Cultural Service of the French Embassy
Australian Research Council
Type of material: Journal Article
Publisher: ACS
Journal: Crystal Growth and Design
Volume: 17
Issue: 12
Start page: 6603
End page: 6612
Copyright (published version): 2017 American Chemical Society
Keywords: MonomerPolypyridylsPolypyridyl solubilityMetal–organic frameworks (MOFs)
DOI: 10.1021/acs.cgd.7b01256
Language: en
Status of Item: Peer reviewed
ISSN: 1528-7483
This item is made available under a Creative Commons License: https://creativecommons.org/licenses/by-nc-nd/3.0/ie/
Appears in Collections:Chemistry Research Collection

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