Now showing 1 - 5 of 5
  • Publication
    Spatial-spectral analysis method using texture features combined with PCA for information extraction in hyperspectral images
    (Wiley, 2020-02) ;
    This work proposes a new method to treat spatial and spectral information interactively. The method extracts spatial features, ie, variogram, gray-level co-occurrence matrix (GLCM), histograms of oriented gradients (HOG), and local binary pattern (LBP) features, from each wavelength image of hypercube and principal component analysis (PCA) is applied on this spatial feature matrix to identify wavelength-dependent variation in spatial patterns. Resultant image is obtained by projecting the score values to the original data. Three datasets, including a synthetic hyperspectral image (Dataset 1), a set of real hyperspectral images of salmon fillets (Dataset 2), and remote-sensing images (Dataset 3), were utilized to evaluate the performance of the proposed method. Results from Dataset 1 showed that the spatial-spectral methods had the potential of reducing baseline offset noise. Dataset 2 revealed that spatial-spectral methods can alleviate noisy pixels with strong signal and reduce shadow effects. In addition, substantial improvements were obtained in case of classification between white stripe and red muscle pixels by using the HOG-based approach with correct classification rate (CCR) of 0.97 compared with the models directly built from raw and standard normal variate (SNV) preprocessed spectra (CCR = 0.94). Samson image of Dataset 3 suggested the flexibility and effectiveness of the proposed method by improving CCR of 0.96 using conventional PCA on SNV pretreated spectra to 0.98 using GLCM-based approach on SNV preprocessed spectra. Overall, experimental results demonstrated that the spatial-spectral methods can improve the results found by using the spectral information alone because of the spatial information provided.
    Scopus© Citations 22  173
  • Publication
    FTIR and Raman imaging for microplastics analysis: State of the art, challenges and prospects
    Despite a substantial body of research to date for the detection of microplastics (MPs) in almost every environmental compartment there remains a lack of standardisation, and methodologies used by different research groups vary widely. Chemical imaging, which provides simultaneous measurement of physical (i.e. spatial) and chemical (i.e. spectroscopic) information, is recognized as a promising tool for MPs analysis. Herein, we first review the state-of-the-art chemical imaging methods, i.e., Fourier-transform infrared spectroscopy (FTIR) and Raman imaging, for the identification and quantification of MPs from different environmental samples. From a technical point of view (e.g., accuracy, speed optimizations and background effects), the limitations and analytical challenges are highlighted from extensive literature data. Finally, we suggest possible strategies and solutions to improve current practices towards an automated routine for MPs analysis.
    Scopus© Citations 315  531
  • Publication
    FTIR Spectroscopy for Molecular Level Description of Water Vapor Sorption in Two Hydrophobic Polymers
    (IEEE, 2019-09-26) ;
    This work aims to investigate the sorption of water vapor in two hydrophobic polymers, i.e., polytetrafluoroethylene (PTFE) and polyurethane (PU) with water contact of 119 and 104, respectively, by using Fourier transform infrared (FTIR) spectroscopy combined with gravimetric analysis. Sample spectra were measured in a controlled humidity cell. Results demonstrated the absence of water molecules in PTFE after exposure to 100% RH for 2 hours. In contrast, the spectroscopic data provided strong evidence that PU film continued to sorb water as exposure time increased. The interaction between water molecules and PU polymer chain was characterized by the dynamics of hydrogen bonding. The hydrogen bonding between N-H and C=O groups was reduced by the sorbed water, as evidenced by the shift of NH to a higher frequency. Second derivative of difference spectra suggested the presence of multiple water species involved in different types of hydrogen bonding interaction at water/PU interface. Results also revealed that the sorbed water in PU film cannot be eliminated via evaporation at room temperature.
    Scopus© Citations 3  340
  • Publication
    Chemometric methods applied in the image plane to correct striping noise in hyperspectral chemical images of biomaterials
    Array detectors improve data collection speed in hyperspectral chemical imaging, yet are prone to striping noise patterns in the image plane, which is difficult to remove. This type of noise affects spectral features and disturbs visual impression of the scene. We found that this type of noise depends on the material composition and setting parameters, ie, pixel size, and it also varies in accordance with the signal intensity of the observed wavelength. To address this, we proposed a new correction method on the basis of the application of chemometric techniques in the image plane of each wavelength. To verify the effectiveness of this method, infrared transmission images of the 2″ × 2″ positive, 1951 USAF Hi‐Resolution Target and biomaterial samples were obtained with a 16‐element (8 × 2) pixel array detector. Point detector images of some samples were also acquired and used as reference images. The proposed correction method produced substantial improvements in the visual impression of intensity images. Principal components analysis was performed to inspect spectral changes after preprocessing, and the results suggested that the major spectral features were not altered while the stripes on intensity images were removed. Spectral profiles and principal components analysis loadings inspection confirmed the smoothing ability of this correction method. As traditional preprocessing techniques, standard normal variate and derivative transformation were not able to remove line artifacts, especially on the biomaterial images. Overall, the proposed method was effective for removing striping noise patterns from infrared images with a minimal alteration of the valuable hyperspectral image information.
    Scopus© Citations 3  154
  • Publication
    Investigation of plasticizer aggregation problem in casein based biopolymer using chemical imaging
    (Elsevier, 2019-02-01) ;
    This work aims to investigate the emergence of aggregates caused by redundant plasticizers in the protein matrix of casein based biopolymers using chemical imaging techniques. Near infrared (NIR) images (950–1671 nm) were first acquired and the spatial variations on macroscale with a pixel size of 0.4 mm × 0.5 mm were visualized. The introduction of plasticizers resulted in a strong hydrogen bonding matrix in the protein polymeric film as evidenced by analysis of Fourier transform near infrared (FT-NIR) spectral profiles in the range of 7500–4000 cm−1. Attenuated total reflectance Fourier transform infrared (ATR-FTIR) images (4000–650 cm−1) coupled with principal components analysis (PCA) and multivariate curve resolution alternating least squares (MCR-ALS) analysis suggested the existence of sorbitol re-crystallization after 5 months storage in the ambient condition. Raman images with a higher pixel size of 1.2 µm × 1.2 µm indicated an uneven film surface caused by sorbitol migration and re-crystallization. A partial least squares (PLS) regression model was developed to predict plasticizer concentration based on the mean spectra of FT-NIR hypercubes, producing coefficient of determination in calibration (R2Cal) of 0.93, cross-validation (R2CV) of 0.92 and prediction (R2P) of 0.89. Visualization of aggregates in the image field was obtained by applying the developed PLS model in a pixel-wise manner using single-element and array detectors. The combined information from NIR and FT-NIR evidenced the occurrence of high plasticizer-concentrated regions in the film sample, while the combined information from FT-NIR and ATR-FTIR further confirms the phenomenon of sorbitol re-crystallization.
    Scopus© Citations 8  201